Organic mesh template-based laminated object manufacturing to fabricate ceramics with regular micron scaled pore structures

A new aqueous slurry-based laminated object manufacturing process for porous ceramics is proposed: firstly, an organic mesh sheet is pre-paved as a pore-forming template before slurry layer scraping; secondly, the 2D pattern is built with laser outline cutting of the dried mesh–ceramic composite layer; finally, the pore structure is formed after degreasing and sintering. Alumina parts with porosities of 51.5 %, round hole diameters of 80 ± 5 μm were fabricated using 70 wt. % solid content slurry and 100 mesh nylon net. Using an organic mesh as the framework and template not only reduces the risk of damage of the green body but also ensures the regularity, uniformity and connectivity of the micron scaled pore network. The layer-by-layer drying method avoids the delamination phenomenon and improves the paving density. The new method can realize the flexible design of the pore structure by using various organic mesh templates.     

Controlled galvanic decoration boosting catalysis: Enhanced glycerol electro-oxidation at Cu/Ni modified macroporous films

We report on glycerol electro-oxidation in alkaline medium at macroporous Ni electrodes decorated with Cu particles. Macroporous Ni film is electrodeposited, using hydrogen bubbles as dynamic templates, atop of a Cu substrate. This film shows good electrocatalytic activity towards glycerol oxidation reaction (GOR). The Ni film is further decorated with Cu via spontaneous deposition from CuSO₄ solution. This is done to enhance the catalytic activity of the film towards GOR. The morphology of the Cu-decorated Ni film is controlled using various additives such as KCl and (NH₄)₂SO₄ which are added to the Cu deposition bath. The as-prepared Cu-decorated Ni films are characterized by electrochemical measurements, scanning electron microscopy (SEM), energy-dispersive X-ray spectroscopy (EDS), X-ray diffraction (XRD), and X-ray photoelectron spectroscopy (XPS). It is found that these additives have tremendous effects on the morphology and the electrocatalytic activity of the decorating Cu particles.The decorated Ni foam showed superior electrocatalytic activity towards the GOR, as confirmed by the negative shift in the onset oxidation potential (ca. 100 mV) together with an increase in oxidation current that is up to 1.5-fold during the cyclic voltammetry (CV) measurements, compared to the undecorated Ni foam.     

软模板法制备多级孔ZSM-5分子筛的研究进展

相比传统ZSM-5分子筛,多级孔ZSM-5分子筛具有空间位阻小、传质效率高、焦炭少等特点,近年来在分子筛领域应用广泛。多级孔分子筛通常可用后处理法和模板剂法制备,相比后处理法,模板剂法能更好地控制介孔的结构和孔道尺寸。概述了采用传统表面活性剂、两亲性的有机硅烷、双功能多季铵盐表面活性剂及高分子聚合物等软模板法合成多级孔ZSM-5分子筛的研究进展。分析不同软模板剂的特点和作用机理,阐述了合成后分子筛的结构特点及催化性能等。指出在今后的研究中,可以设计价格较低的新型功能化模板剂,优化合成过程,致力于在理解合成机理的前提下,寻找操作简单、绿色环保的合成路线,并将其推行到实际工业生产中。     

Texturing behaviours of (K0.47Na0.51Li0.02)(Nb0.8Ta0.2)O3 piezoelectric ceramics produced using NaNb1-xTaxO3 templates

Textured (K_0.47Na_0.51Li_0.02)(Nb_0.8Ta_0.2)O₃ (KNLNT20) piezoelectric ceramics were prepared using NaNb_1?xTa_xO₃ templates. The highest degree of grain orientation (97%) and piezoelectric constant (342 pC/N) were obtained upon adding 3 wt% of the NaNb_0.8Ta_0.2O₃ (NNT20) template and sintering at 1150 °C for 1 h. Back-scattered scanning electron micrographs of the textured KNLNT20 samples sintered at 1150 °C for 1 h indicated the presence of templates similar in size to the original ones within the cores of the textured grains. The peak value of the dielectric constant corresponding to the NNT20 core decreased after prolonged holding at 1150 °C, owing to a decrease in the size of the NNT20 core because of the interdiffusion of K, Na, and Li ions between the NNT20 core and KNLNT20 shell. This interdiffusion also decreased the piezoelectric constant, d₃₃ value of the textured KNLNT20 samples by inducing a change in the chemical composition of the shell region.     

中空微/纳米结构材料的制备及其在超级电容器领域的应用

对近年来中空微/纳米结构材料的制备方法及其在超级电容器领域的应用进行综述。介绍了中空微/纳米结构材料的制备方法,包括:硬模板法、软模板法和无模板法,概述了中空微/纳米结构材料在超级电容器领域的应用,总结了中空微/纳米结构材料在超级电容器领域应用中存在的一些不足。     

Template Engineering of CuBi2O4 Single‐Crystal Thin Film Photocathodes

To develop strategies for efficient photo‐electrochemical water‐splitting, it is important to understand the fundamental properties of oxide photoelectrodes by synthesizing and investigating their single‐crystal thin films. However, it is challenging to synthesize high‐quality single‐crystal thin films from copper‐based oxide photoelectrodes due to the occurrence of significant defects such as copper or oxygen vacancies and grains. Here, the CuBi₂O₄ (CBO) single‐crystal thin film photocathode is achieved using a NiO template layer grown on single‐crystal SrTiO₃ (STO) (001) substrate via pulsed laser deposition. The NiO template layer plays a role as a buffer layer of large lattice mismatch between CBO and STO (001) substrate through domain‐matching epitaxy, and forms a type‐II band alignment with CBO, which prohibits the transfer of photogenerated electrons toward bottom electrode. The photocurrent densities of the CBO single‐crystal thin film photocathode demonstrate ?0.4 and ?0.7 mA cm^?2 at even 0 V_RHE with no severe dark current under illumination in a 0.1 m potassium phosphate buffer solution without and with H₂O₂ as an electron scavenger, respectively. The successful synthesis of high‐quality CBO single‐crystal thin film would be a cornerstone for the in‐depth understanding of the fundamental properties of CBO toward efficient photo‐electrochemical water‐splitting.     

一种改进的灰度匹配新算法

灰度匹配新算法是在传统算法基础上改进而来。它先根据信息量的大小选取部分影像进行粗匹配,粗匹配通过后再用相关系数法进行精匹配。实验表明,本文所提出的方法较现存的方法精度高、速度快。     

CAPP系统开发过程中工艺卡片定制问题的研究

本文设计的工艺卡片定制模块,能够使用户方便地定制自己本企业所需要的格式模板,从而使CAPP系统的开发研究更趋于商品化．     

关于三峡库区周边坡体岩石特性的考察

岩石强度的载荷速率相关性与岩石的时间相关性特性及粘弹性性质密切相关，而且强度的栽荷速率相关性越大，越容易发生蠕变破坏。对于坡体来说，如果构成坡体的岩石的时间相关性很显著．那么即使在比较低的应力下仅施加一点载荷，也容易发生变形。针对三峡库区周边滑坡多发，采集了组成滑坡坡体的4类主要岩石-泥岩、灰岩、泥质砂岩及砂岩。通过室内岩石力学强度试验，获得了不同岩石的强度特性曲线及表示载荷速率相关性的参数n。利用一个试件通过载荷速率交替变换获得了不同应变速率下的应力-应变曲线，从而根据强度的变化率不仅获得了峰值强度的载荷速率相关性，而且还求得了残余强度的载荷速率相关性。在单轴压缩试验中，残余强度的n值与峰值强度的n值有较大的差异，但在三轴压缩试验中两者的差异却不太明显。而且在气干状态下，不管是峰值强度还是残余强度的n值均随着围压的增加而增加。     

砖砌体结构在小震下的失效相关性分析

本文运用可靠度理论,依据我国现行的砌体结构设计规范,建立起抗震和非抗震的砖砌体墙的试验模型。采用Monte-Carlo随机模拟法,在水平地震作用下对两类(抗震和非抗震)砖墙模型进行了分析。根据统计学原理,总结出小震下砖砌体墙的失效规律和失效相关性规律。以期为砌体结构的可靠性分析、抗震加固及震后维修等理论提供具有参考意义的分析依据。